IB Chemistry Syllabus SL & HL

IB Chemistry Syllabus

Complete, up-to-date and broken down by sub-topics for the IB Chemistry SL and IB Chemistry HL courses!

IB Chemistry Syllabus SL & HL

Topic 1: Stoichiometric Relationships

This section of the IB Chemistry syllabus focuses on the concept of moles and how this can be used in calculations throughout the IB Chemistry syllabus and the sub-topics within.

Understanding

Application

1.1: The particulate nature of matter and chemical change

(1) Atoms of different elements combine in fixed ratios to form compounds, which have different properties from their component elements (2) Mixtures contain more than one element and/or compound that are not chemically bonded together and so retain their individual properties (3) Mixtures are either homogeneous or heterogeneous
(1) Deduction of chemical equations when reactants and products are specified (2) Application of the state symbols (s), (l), (g) and (aq) in equations (3) Explanation of observable changes in physical properties and temperature during changes of state

1.2: The mole concept

(1) The mole is a fixed number of particles and refers to the amount, n, of substance (2) Masses of atoms are compared on a scale relative to 12C and are expressed as relative atomic mass (Ar) and relative formula/molecular mass (Mr) (3) Molar mass (M) has the units g mol-1 (4) The empirical formula and molecular formula of a compound give the simplest ratio and the actual number of atoms present in a molecule respectively
(1) Calculation of the molar masses of atoms, ions, molecules, and formula units (2) Solution of problems involving the relationships between the number of particles, the amount of substance in moles and the mass in grams (3) Interconversion of the percentage composition by mass and the empirical formula (4) Determination of the molecular formula of a compound from its empirical formula and molar mass (5) Obtaining and using experimental data for deriving empirical formulas from reactions involving mass changes

1.3: Reacting masses and volumes

(1) Reactants can be either limiting or excess (2) The experimental yield can be different from the theoretical yield (3) Avogadro’s law enables the mole ratio of reacting gases to be determined from volumes of the gases (4) The molar volume of an ideal gas is a constant at specified temperature and pressure (5) The molar concentration of a solution is determined by the amount of solute and the volume of solution (6) A standard solution is one of known concentration
(1) Solution of problems relating to reacting quantities, limiting and excess reactants, theoretical, experimental and percentage yields (2) Calculation of reacting volumes of gases using Avogadro’s law (3) Solution of problems and analysis of graphs involving the relationship between temperature, pressure, and volume for a fixed mass of an ideal gas (4) Solution of problems relating to the ideal gas equation (5) Explanation of the deviation of real gases from ideal behaviour at low temperature and high pressure (6) Obtaining and using experimental values to calculate the molar mass of a gas from the ideal gas equation (7) Solution of problems involving molar concentration, amount of solute and volume of solution (8) Use of the experimental method of titration to calculate the concentration of a solution by reference to a standard solution

Topic 2 & 12: Atomic Structure

This section of the IB Chemistry syllabus focuses on the structure of atoms, in particular electrons, and how these influence properties explored throughout the IB Chemistry syllabus and the sub-topics within.

Understanding

Application

2.1: The nuclear atom

(1) Atoms contain a positively charged dense nucleus composed of protons and neutrons (nucleons) (2) Negatively charged electrons occupy the space outside the nucleus (3) The mass spectrometer is used to determine the relative atomic mass of an element from its isotopic composition

(1) Use of the nuclear symbol notation to deduce the number of protons, neutrons and electrons in atoms and ions

(2) Calculations involving non-integer relative atomic masses and abundance of isotopes from given data, including mass spectra

2.2: Electronic configuration

(1) Emission spectra are produced when photons are emitted from atoms as excited electrons return to a lower energy level

(2) The line emission spectrum of hydrogen provides evidence for the existence of electrons in discrete energy levels, which converge at higher energies

(3) The main energy level or shell is given an integer number, n, and can hold a maximum number of electrons

(4) A more detailed model of the atom describes the division of the main energy level into s, p, d, and f sub-levels of successively higher energies

(5) Sub-levels contain a fixed number of orbitals, regions of space where there is a high probability of finding an electron

(6) Each orbital has a defined energy state for a given electronic configuration and chemical environment and can hold two electrons of opposite spin

(1) Description of the relationship between colour, wavelength, frequency, and energy across the electromagnetic spectrum (2) Distinction between a continuous spectrum and a line spectrum (3) Description of the emission spectrum of the hydrogen atom, including the relationships between the lines and energy transitions to the first, second and third energy levels (4) Recognition of the shape of an s atomic orbital and the px, py and pz atomic orbitals (5) Application of the Aufbau principle, Hund’s rule, and the Pauli exclusion principle to write electron configurations for atoms and ions up to Z = 36

12.1: Electrons in atoms (Higher Level)

(1) In an emission spectrum, the limit of convergence at higher frequency corresponds to the first ionization energy (2) Trends in first ionization energy across periods account for the existence of main energy levels and sub-levels in atoms (3) Successive ionization energy data for an element give information that shows relations to electron configurations
(1) Solving problems using E = hv (2) Calculation of the value of the first ionization energy from spectral data which gives the wavelength or frequency of the convergence limit (3) Deduction of the group of an element from its successive ionization energy data (4) Explanation of the trends and discontinuities in first ionization energy across a period

Topic 3 & 13: Periodicity

This section of the IB Chemistry syllabus focuses on the main physical trends observed within the periodic table. It discusses these with reference to other topics from the IB Chemistry syllabus.

Understanding

Application

3.1: Periodic table

(1) The periodic table is arranged into four blocks associated with the four sub- levels—s, p, d, and f (2) The periodic table consists of groups (vertical columns) and periods (horizontal rows) (3) The period number (n) is the outer energy level that is occupied by electrons (4) The number of the principal energy level and the number of the valence electrons in an atom can be deduced from its position on the periodic table (5) The periodic table shows the positions of metals, non-metals, and metalloids
(1) Deduction of the electron configuration of an atom from the element’s position on the periodic table, and vice versa

3.2: Periodic trends

(1) Vertical and horizontal trends in the periodic table exist for atomic radius, ionic radius, ionization energy, electron affinity and electronegativity (2) Trends in metallic and non-metallic behaviour are due to the trends above (3) Oxides change from basic through amphoteric to acidic across a period

(1) Prediction and explanation of the metallic and non-metallic behaviour of an element based on its position in the periodic table

(2) Discussion of the similarities and differences in the properties of elements in the same group, with reference to alkali metals (group 1) and halogens (group 17)

(3) Construction of equations to explain the pH changes for reactions of oxides with water

13.1: First-row d-block elements (Higher Level)

(1) Transition elements have variable oxidation states, form complex ions with ligands, have coloured compounds, and display catalytic and magnetic properties (2) Zn is not considered to be a transition element as it does not form ions with incomplete d-orbitals (3) Transition elements show an oxidation state of +2 when the s- electrons are removed
(1) Explanation of the ability of transition metals to form variable oxidation states from successive ionization energies (2) Explanation of the nature of the coordinate bond within a complex ion (3) Deduction of the total charge given the formula of the ion and ligands present (4) Explanation of the magnetic properties in transition metals in terms of unpaired electrons

13.2: Coloured complexes (Higher Level)

(1) The d sub-level splits into two sets of orbitals of different energy in a complex ion (2) Complexes of d-block elements are coloured, as light is absorbed when an electron is excited between the d- orbitals (3) The colour absorbed is complementary to the colour observed
(1) Explanation of the effect of the identity of the metal ion, the oxidation number of the metal and the identity of the ligand on the colour of transition metal ion complexes (2) Explanation of the effect of different ligands on the splitting of the d-orbitals in transition metal complexes and colour observed using the spectrochemical series

Topic 4 & 14: Chemical Bonding & Structure

This section of the IB Chemistry syllabus focuses on the chemical bonds that form between many molecules and the impact these have upon their shapes. It links to later topics of the IB Chemistry syllabus, such as organics.

Understanding

Application

4.1: Ionic bonding and structure

(1) Positive ions (cations) form by metals losing valence electrons (2) Negative ions (anions) form by non- metals gaining electrons (3) The number of electrons lost or gained is determined by the electron configuration of the atom (4) The ionic bond is due to electrostatic attraction between oppositely charged ions (5) Under normal conditions, ionic compounds are usually solids with lattice structures
(1) Deduction of the formula and name of an ionic compound from its component ions, including polyatomic ions (2) Explanation of the physical properties of ionic compounds (volatility, electrical conductivity, and solubility) in terms of their structure

4.2: Covalent bonding

(1) A covalent bond is formed by the electrostatic attraction between a shared pair of electrons and the positively charged nuclei (2) Single, double, and triple covalent bonds involve one, two and three shared pairs of electrons respectively (3) Bond length decreases, and bond strength increases as the number of shared electrons increases (4) Bond polarity results from the difference in electronegativities of the bonded atoms
(1) Deduction of the polar nature of a covalent bond from electronegativity values

4.3: Covalent structures

(1) Lewis (electron dot) structures show all the valence electrons in a covalently bonded species (2) The “octet rule” refers to the tendency of atoms to gain a valence shell with a total of 8 electrons (3) Some atoms, like Be and B, might form stable compounds with incomplete octets of electrons (4) Resonance structures occur when there is more than one possible position for a double bond in a molecule (5) Shapes of species are determined by the repulsion of electron pairs according to VSEPR theory (6) Carbon and silicon form giant covalent/network covalent structures

(1) Deduction of Lewis (electron dot) structure of molecules and ions showing all valence electrons for up to four electron pairs on each atom

(2) The use of VSEPR theory to predict the electron domain geometry and the molecular geometry for species with two, three and four electron domains

(3) Prediction of bond angles from molecular geometry and presence of non- bonding pairs of electrons

(4) Prediction of molecular polarity from bond polarity and molecular geometry

(5) Deduction of resonance structures

(7) Explanation of the properties of giant covalent compounds in terms of their structures

4.4: Intermolecular forces

(1) Intermolecular forces include London (dispersion) forces, dipole- dipole forces, and hydrogen bonding (2) The relative strengths of these interactions from weakest to strongest are: London (dispersion) forces, dipole-dipole forces, hydrogen bonds
(1) Deduction of the types of intermolecular force present in substances, based on their structure and chemical formula (2) Explanation of the physical properties of covalent compounds (volatility, electrical conductivity, and solubility) in terms of their structure and intermolecular forces

4.5: Metallic bonding

(1) A metallic bond is the electrostatic attraction between a lattice of positive ions and delocalized electrons (2) The strength of a metallic bond depends on the charge of the ions and the radius of the metal ion (3) Alloys usually contain more than one metal and have enhanced properties
(1) Explanation of electrical conductivity and malleability in metals (2) Explanation of trends in melting points of metals (3) Explanation of the properties of alloys in terms of non-directional bonding

14.1: Covalent bonding, electron domains and geometry (Higher Level)

(1) Covalent bonds result from the overlap of atomic orbitals. A sigma bond (σ) is formed by the direct head- on/end-to-end overlap of atomic orbitals, resulting in electron density concentrated between the nuclei of the bonding atoms. A pi bond (π) is formed by the sideways overlap of atomic orbitals, resulting in electron density above and below the plane of the nuclei of the bonding atoms (2) Formal charge (FC) can be used to decide which Lewis (electron dot) structure is preferred from several. The FC is the charge an atom would have if all atoms in the molecule had the same electronegativity. FC = (Number of valence electrons)-1⁄2(Number of bonding electrons)-(Number of non- bonding electrons). The Lewis (electron dot) structure with the atoms having FC values closest to zero is preferred (3) Exceptions to the octet rule include some species having incomplete octets and expanded octets (4) Delocalization involves electrons that are shared by/between all atoms in a molecule or ion as opposed to being localized between a pair of atoms (5) Resonance involves using two or more Lewis (electron dot) structures to represent a particular molecule or ion. A resonance structure is one of two or more alternative Lewis (electron dot) structures for a molecule or ion that cannot be described fully with one Lewis (electron dot) structure alone

(1) Prediction whether sigma (σ) or pi (π) bonds are formed from the linear combination of atomic orbitals

(2) Deduction of the Lewis (electron dot) structures of molecules and ions showing all valence electrons for up to six electron pairs on each atom

(3) Application of FC to ascertain which Lewis (electron dot) structure is preferred from different Lewis (electron dot) structures

(4) Deduction using VSEPR theory of the electron domain geometry and molecular geometry with five and six electron domains and associated bond angles

(5) Explanation of the wavelength of light required to dissociate oxygen and ozone

(6) Description of the mechanism of the catalysis of ozone depletion when catalysed by CFCs and NOX’s

14.2: Hybridisation (Higher Level)

(1) A hybrid orbital results from the mixing of different types of atomic orbitals on the same atom
(1) Explanation of the formation of sp3, sp2 and sp hybrid orbitals in methane, ethene and ethyne (2) Identification and explanation of the relationships between Lewis (electron dot) structures, electron domains, molecular geometries, and types of hybridization

Topic 5 & 15: Energetics/Thermochemistry

This section of the IB Chemistry syllabus explores the energy changes accompanying chemical reactions that are discussed throughout the IB Chemistry syllabus.

Understanding

Application

5.1: Measuring energy changes

(1) Heat is a form of energy (2) Temperature is a measure of the average kinetic energy of the particles (3) Total energy is conserved in chemical reactions (4) Chemical reactions that involve transfer of heat between the system and the surroundings are described as endothermic or exothermic (5) The enthalpy change (∆H) for chemical reactions is in kJmol-1 (6) ∆H values are usually expressed under standard conditions, given ΔH°, including standard states
(1) Calculation of the heat change when the temperature of a pure substance is changed using q = mcΔT (2) A calorimetry experiment for an enthalpy of reaction should be covered and the results evaluated

5.2: Hess’s law

(1) The enthalpy change for a reaction that is carried out in a series of steps is equal to the sum of the enthalpy changes for the individual steps
(1) Application of Hess’s Law to calculate enthalpy changes (2) Calculation of ΔH reactions using ∆H° data (3) Determination of the enthalpy change of a reaction that is the sum of multiple reactions with known enthalpy changes

5.3: Bond enthalpies

(1) Bond-forming releases energy and bond-breaking requires energy (2) Average bond enthalpy is the energy needed to break one mol of a bond in a gaseous molecule averaged over similar compounds
(1) Calculation of the enthalpy changes from known bond enthalpy values and comparison of these to experimentally measured values (2) Sketching and evaluation of potential energy profiles in determining whether reactants or products are more stable and if the reaction is exothermic or endothermic (3) Discussion of the bond strength in ozone relative to oxygen in its importance to the atmosphere

15.1: Energy cycles (Higher Level)

(1) Representative equations can be used for enthalpy/energy of hydration, ionization, atomization, electron affinity, lattice, covalent bond and solution (2) Enthalpy of solution, hydration enthalpy and lattice enthalpy are related in an energy cycle
(1) Construction of Born-Haber cycles for group 1 and 2 oxides and chlorides (2) Construction of energy cycles from hydration, lattice, and solution enthalpy. For example, dissolution of solid NaOH or NH4Cl in water (3) Calculation of enthalpy changes from Born-Haber or dissolution energy cycles (4) Relate size and charge of ions to lattice and hydration enthalpies (5) Perform lab experiments which could include single replacement reactions in aqueous solutions

15.2: Entropy and spontaneity (Higher Level)

(1) Entropy (S) refers to the distribution of available energy among the particles. The more ways the energy can be distributed the higher the entropy (2) Gibbs free energy (G) relates the energy that can be obtained from a chemical reaction to the change in enthalpy (ΔH), change in entropy (ΔS), and absolute temperature (T) (3) Entropy of gas>liquid>solid under same conditions
(1) Prediction of whether a change will result in an increase or decrease in entropy by considering the states of the reactants and products (2) Calculation of entropy changes (ΔH) from given standard entropy values (S°) (3) Application of ΔG° = ΔH° – TΔS° in predicting spontaneity and calculation of various conditions of enthalpy and temperature that will affect this (4) Relation of ΔG to position of equilibrium

Topic 6 & 16: Chemical Kinetics

This section of the IB Chemistry syllabus focuses on the speed of reactions and how this relates to chemical pathways detailed throughout the IB Chemistry syllabus and the sub-topics within.

Understanding

Application

6.1: Collision theory and rates of reaction

(1) Species react as a result of collisions of sufficient energy and proper orientation (2) The rate of reaction is expressed as the change in concentration of a particular reactant/product per unit time (3) Concentration changes in a reaction can be followed indirectly by monitoring changes in mass, volume, and colour (4) Activation energy (Ea) is the minimum energy that colliding molecules need in order to have successful collisions leading to a reaction (5) By decreasing Ea, a catalyst increases the rate of a chemical reaction, without itself being permanently chemically changed

(1) Description of the kinetic theory in terms of the movement of particles whose average kinetic energy is proportional to temperature in Kelvin

(2) Analysis of graphical and numerical data from rate experiments

(3) Explanation of the effects of temperature, pressure/concentration, and particle size on rate of reaction

(4) Construction of Maxwell–Boltzmann energy distribution curves to account for the probability of successful collisions and factors affecting these, including the effect of a catalyst

(5) Investigation of rates of reaction experimentally and evaluation of the results (6) Sketching and explanation of energy profiles with and without catalysts

16.1: Rate expression and reaction mechanism (Higher Level)

(1) Reactions may occur by more than one step and the slowest step determines the rate of reaction (rate determining step/RDS)

(2) The molecularity of an elementary step is the number of reactant particles taking part in that step

(3) The order of a reaction can be either integer or fractional in nature. The order of a reaction can describe, with respect to a reactant, the number of particles taking part in the rate-determining step

(4) Rate equations can only be determined experimentally

(5) The value of the rate constant (k) is affected by temperature and its units are determined from the overall order of the reaction

(6) Catalysts alter a reaction mechanism, introducing a step with lower activation energy

(1) Deduction of the rate expression for an equation from experimental data and solving problems involving the rate expression (2) Sketching, identifying, and analysing graphical representations for zero, first and second order reactions (3) Evaluation of proposed reaction mechanisms to be consistent with kinetic and stoichiometric data

16.2: Activation energy (Higher Level)

(1) The Arrhenius equation uses the temperature dependence of the rate constant to determine the activation energy (2) A graph of 1/T against ln k is a linear plot with gradient – Ea/RT and intercept, ln A (3) The frequency factor (or pre- exponential factor) (A) takes into account the frequency of collisions with proper orientations
(1) Analysing graphical representation of the Arrhenius equation in its linear form (2) Using the Arrhenius equation (3) Describing the relationships between temperature and rate constant; frequency factor and complexity of molecules colliding (4) Determining and evaluating values of activation energy and frequency factors from data

Topic 7 & 17: Equilibrium

This section of the IB Chemistry syllabus covers the concept of equilibrium, with reference to chemical reactions as seen elsewhere in the IB Chemistry syllabus.

Understanding

Application

7.1: Equilibrium

(1) A state of equilibrium is reached in a closed system when the rates of the forward and reverse reactions are equal (2) The equilibrium law describes how the equilibrium constant (Kc) can be determined for a particular chemical reaction (3) The magnitude of the equilibrium constant indicates the extent of a reaction at equilibrium and is temperature dependent (4) The reaction quotient (Q) measures the relative amount of products and reactants present during a reaction at a particular point in time. Q is the equilibrium expression with non- equilibrium concentrations. The position of the equilibrium changes with changes in concentration, pressure, and temperature (5) A catalyst has no effect on the position of equilibrium or the equilibrium constant

(1) The characteristics of chemical and physical systems in a state of equilibrium

(2) Deduction of the equilibrium constant expression (Kc) from an equation for a homogeneous reaction

(3) Determination of the relationship between different equilibrium constants (Kc) for the same reaction at the same temperature

(4) Application of Le Châtelier’s principle to predict the qualitative effects of changes of temperature, pressure, and concentration on the position of equilibrium and on the value of the equilibrium constant

17.1: The equilibrium law (Higher Level)

(1) Le Châtelier’s principle for changes in concentration can be explained by the equilibrium law (2) The position of equilibrium corresponds to a maximum value of entropy and a minimum in the value of the Gibbs free energy (3) The Gibbs free energy change of a reaction and the equilibrium constant can both be used to measure the position of an equilibrium reaction and are related by the equation, ΔG = -RTlnK
(1) Solution of homogeneous equilibrium problems using the expression for Kc (2) Relationship between ΔG and the equilibrium constant (3) Calculations using the equation ΔG = – RTlnK

Topic 8 & 18: Acids & bases

This section of the IB Chemistry syllabus discusses the concept of acids and bases and how they can react with many of the chemicals and compounds seen earlier in the IB Chemistry syllabus.

Understanding

Application

8.1: Theories of acids and bases

(1) A Brønsted–Lowry acid is a proton/H+ donor and a Brønsted–Lowry base is a proton/H+ acceptor (2) Amphiprotic species can act as both Brønsted–Lowry acids and bases (3) A pair of species differing by a single proton is called a conjugate acid-base pair
(1) Deduction of the Brønsted–Lowry acid and base in a chemical reaction (2) Deduction of the conjugate acid or conjugate base in a chemical reaction

8.2: Properties of acids and bases

(1) Most acids have observable characteristic chemical reactions with reactive metals, metal oxides, metal hydroxides, hydrogen carbonates and carbonates (2) Salt and water are produced in exothermic neutralization reactions
(1) Balancing chemical equations for the reaction of acids (2) Identification of the acid and base needed to make different salts (3) Candidates should have experience of acid-base titrations with different indicators

8.3: The pH scale

(1) pH = -log[H+(aq)] and [H+] = 10^-pH (2) A change of one pH unit represents a 10-fold change in the hydrogen ion concentration [H+] (3) pH values distinguish between acidic, neutral, and alkaline solutions. (4) The ionic product constant, Kw = [H+][OH-] = 10^-14 at 298K
(1) Solving problems involving pH, [H+] and [OH-] (2) Students should be familiar with the use of a pH meter and universal indicator

8.4: Strong and weak acids and bases

(1) Strong and weak acids and bases differ in the extent of ionization (2) Strong acids and bases of equal concentrations have higher conductivities than weak acids and bases (3) A strong acid is a good proton donor and has a weak conjugate base (4) A strong base is a good proton acceptor and has a weak conjugate acid
(1) Distinction between strong and weak acids and bases in terms of the rates of their reactions with metals, metal oxides, metal hydroxides, metal hydrogen carbonates and metal carbonates and their electrical conductivities for solutions of equal concentrations

8.5: Acid deposition

(1) Rain is naturally acidic because of dissolved CO2 and has a pH of 5.6. Acid deposition has a pH below 5.6 (2) Acid deposition is formed when nitrogen or sulphur oxides dissolve in water (3) Sources of the oxides of sulphur and nitrogen and the effects of acid deposition should be covered
(1) Balancing the equations that describe the combustion of sulphur and nitrogen to their oxides (2) Distinction between the pre-combustion and post-combustion methods of reducing sulphur oxides emissions (3) Deduction of acid deposition equations for acid deposition with reactive metals and carbonates

18.1: Lewis acids and bases (Higher Level)

(1) A Lewis acid is a lone pair acceptor and a Lewis base is a lone pair donor (2) When a Lewis base reacts with a Lewis acid a coordinate bond is formed (3) A nucleophile is a Lewis base and an electrophile is a Lewis acid
(1) Application of Lewis’ acid–base theory to inorganic and organic chemistry to identify the role of the reacting species

18.2: Calculations involving acids and bases (Higher Level)

(1) The expression for the dissociation constant of a weak acid (Ka) and a weak base (Kb) (2) For a conjugate acid base pair, Ka x Kb = Kw (3) The relationship between Ka and pKa is (pKa = -log Ka), and between Kb and pKb is (pKb = -log Kb)
(1) Solution of problems involving [H+ (aq)], [OH–(aq)], pH, pOH, Ka, pKa, Kb and pKb (2) Discussion of the relative strengths of acids and bases using values of Ka, pKa, Kb and pKb

18.3: pH curves (Higher Level)

(1) The characteristics of the pH curves produced by the different combinations of strong and weak acids and bases (2) An acid–base indicator is a weak acid or a weak base where the components of the conjugate acid–base pair have different colours (3) The relationship between the pH range of an acid–base indicator, which is a weak acid, and its pKa value (4) The buffer region on the pH curve represents the region where small additions of acid or base result in little or no change in pH (5) The composition and action of a buffer solution
(1) The general shapes of graphs of pH against volume for titrations involving strong and weak acids and bases with an explanation of their important features (2) Selection of an appropriate indicator for a titration, given the equivalence point of the titration and the end point of the indicator (3) While the nature of the acid–base buffer always remains the same, buffer solutions can be prepared by either mixing a weak acid/base with a solution of a salt containing its conjugate, or by partial neutralization of a weak acid/base with a strong acid/base (4) Prediction of the relative pH of aqueous salt solutions formed by the different combinations of strong and weak acid and base

Topic 9 & 19: Redox Processes

This section of the IB Chemistry syllabus focuses on the processes of oxidation and reduction, as seen in most of the reactions discussed throughout the IB Chemistry syllabus and the sub-topics within.

Understanding

Application

9.1: Oxidation and reduction

(1) Oxidation and reduction can be considered in terms of oxygen gain/hydrogen loss, electron transfer or change in oxidation number (2) An oxidizing agent is reduced and a reducing agent is oxidized (3) Variable oxidation numbers exist for transition metals and for most main- group non-metals (4) The activity series ranks metals according to the ease with which they undergo oxidation (5) The Winkler Method can be used to measure biochemical oxygen demand (BOD), used as a measure of the degree of pollution in a water sample
(1) Deduction of the oxidation states of an atom in an ion or a compound (2) Deduction of the name of a transition metal compound from a given formula, applying oxidation numbers represented by Roman numerals (3) Identification of the species oxidized and reduced and the oxidizing and reducing agents, in redox reactions (4) Deduction of redox reactions using half- equations in acidic or neutral solutions (5) Deduction of the feasibility of a redox reaction from the activity series or reaction data (6) Solution of a range of redox titration problems (7) Application of the Winkler Method to calculate BOD

9.2: Introduction to electrochemical cells

(1) Voltaic (Galvanic) cells convert energy from spontaneous, exothermic chemical processes to electrical energy (2) Oxidation occurs at the anode (negative electrode) and reduction occurs at the cathode (positive electrode) in a voltaic cell (3) Electrolytic cells convert electrical energy to chemical energy, by bringing about non-spontaneous processes (4) Oxidation occurs at the anode (positive electrode) and reduction occurs at the cathode (negative electrode) in an electrolytic cell
(1) Construction and annotation of both types of electrochemical cells (2) Explanation of how a redox reaction is used to produce electricity in a voltaic cell and how current is conducted in an electrolytic cell (3) Distinction between electron and ion flow in both electrochemical cells (4) Performance of laboratory experiments involving a typical voltaic cell using two metal/metal-ion half-cells (5) Deduction of the products of the electrolysis of a molten salt

19.1: Electrochemical cells (Higher Level)

(1) A voltaic cell generates an electromotive force (EMF) resulting in the movement of electrons from the anode (negative electrode) to the cathode (positive electrode) via the external circuit. The EMF is termed the cell potential (E°) (2) The standard hydrogen electrode (SHE) consists of an inert platinum electrode in contact with 1 mol dm-3 hydrogen ion and hydrogen gas at 100 kPa and 298 K. The standard electrode potential (E°) is the potential (voltage) of the reduction half-equation under standard conditions measured relative to the SHE. Solute concentration is 1 mol dm-3 or 100 kPa for gases. E° of the SHE is 0V (3) When aqueous solutions are electrolysed, water can be oxidized to oxygen at the anode and reduced to hydrogen at the cathode (4) ΔG° = -nFE° when E° is positive, ΔG° is negative indicative of a spontaneous process. When E° is negative, ΔG° is positive indicative of a non- spontaneous process. When E° is 0, then ΔG° is 0 (5) Current, duration of electrolysis and charge on the ion affect the amount of product formed at the electrodes during electrolysis (6) Electroplating involves the electrolytic coating of an object with a metallic thin layer

(1) Calculation of cell potentials using standard electrode potentials

(2) Prediction of whether a reaction is spontaneous or not using E° values

(3) Determination of standard free-energy changes (ΔG°) using standard electrode potentials

(4) Explanation of the products formed during the electrolysis of aqueous solutions

(5) Perform lab experiments that could include single replacement reactions in aqueous solutions

(6) Determination of the relative amounts of products formed during electrolytic processes

(7) Explanation of the process of electroplating

Topic 10 & 20: Organic Chemistry

This section of the IB Chemistry syllabus covers a vast range of content relating to organic compounds, their proerties and their reactions. It requires knowledge from elsewhere in the IB Chemistry syllabus, such as bonding.

Understanding

Application

10.1: Fundamentals of organic chemistry

(1) A homologous series is a series of compounds of the same family, with the same general formula, which differ from each other by a common structural unit (2) Structural formulas can be represented in full and condensed format (3) Structural isomers are compounds with the same molecular formula but different arrangements of atoms (4) Functional groups are the reactive parts of molecules (5) Saturated compounds contain single bonds only and unsaturated compounds contain double or triple bonds (6) Benzene is an aromatic, unsaturated hydrocarbon.
(1) Explanation of the trends in boiling points of members of a homologous series (2) Distinction between empirical, molecular, and structural formulas (3) Identification of different classes: alkanes, alkenes, alkynes, halogenoalkanes, alcohols, ethers, aldehydes, ketones, esters, carboxylic acids, amines, amides, nitriles and arenes (4) Identification of typical functional groups in molecules eg phenyl, hydroxyl, carbonyl, carboxyl, carboxamide, aldehyde, ester, ether, amine, nitrile, alkyl, alkenyl and alkynyl (5) Construction of 3-D models (real or virtual) of organic molecules (6) Application of IUPAC rules in the nomenclature of straight-chain and branched-chain isomers (7) Identification of primary, secondary and tertiary carbon atoms in halogenoalkanes and alcohols and primary, secondary, and tertiary nitrogen atoms in amines (8) Discussion of the structure of benzene using physical and chemical evidence

10.2: Functional group chemistry

(1) Alkanes have low reactivity and undergo free-radical substitution reactions (2) Alkenes are more reactive than alkanes and undergo addition reactions. Bromine water can be used to distinguish between alkenes and alkanes (3) Alcohols undergo nucleophilic substitution reactions with acids (also called esterification or condensation) and some undergo oxidation reactions (4) Halogenoalkanes are more reactive than alkanes. They can undergo (nucleophilic) substitution reactions. A nucleophile is an electron-rich species containing a lone pair that it donates to an electron-deficient carbon (5) Addition polymers consist of a wide range of monomers and form the basis of the plastics industry (6) Benzene does not readily undergo addition reactions but does undergo electrophilic substitution reactions
(1) Writing equations for the complete and incomplete combustion of hydrocarbons (2) Explanation of the reaction of methane and ethane with halogens in terms of a free- radical substitution mechanism involving photochemical homolytic fission (3) Writing equations for the reactions of alkenes with hydrogen and halogens and of symmetrical alkenes with hydrogen halides and water (4) Outline of the addition polymerization of alkenes (5) Relationship between the structure of the monomer to the polymer and repeating unit (6) Writing equations for the complete combustion of alcohols (7) Writing equations for the oxidation reactions of primary and secondary alcohols (using acidified potassium dichromate (VI) or potassium manganate (VII) as oxidizing agents) (8) Explanation of distillation and reflux in the isolation of the aldehyde and carboxylic acid products (9) Writing the equation for the condensation reaction of an alcohol with a carboxylic acid, in the presence of a catalyst (eg concentrated sulfuric acid) to form an ester (10) Writing the equation for the substitution reactions of halogenoalkanes with aqueous sodium hydroxide

20.1: Types of organic reactions (Higher Level)

(1) SN1 represents a nucleophilic unimolecular substitution reaction and SN2 represents a nucleophilic bimolecular substitution reaction. (2) SN1 involves a carbocation intermediate. SN2 involves a concerted reaction with a transition state (3) For tertiary halogenoalkanes the predominant mechanism is SN1 and for primary halogenoalkanes it is SN2. Both mechanisms occur for secondary halogenoalkanes (4) The rate determining step (slow step) in an SN1 reaction depends only on the concentration of the halogenoalkane, rate = k[halogenoalkane]. For SN2, rate = k[halogenoalkane][nucleophile] (5) SN2 is stereospecific with an inversion of configuration at the carbon (6) SN2 reactions are best conducted using aprotic, non-polar solvents and SN1 reactions are best conducted using protic, polar solvents (7) An electrophile is an electron- deficient species that can accept electron pairs from a nucleophile. Electrophiles are Lewis acids (8) Markovnikov’s rule can be applied to predict the major product in electrophilic addition reactions of unsymmetrical alkenes with hydrogen halides and interhalogens. The formation of the major product can be explained in terms of the relative stability of possible carbocations in the reaction mechanism (9) Benzene is the simplest aromatic hydrocarbon compound (or arene) and has a delocalized structure of π bonds around its ring. Each carbon to carbon bond has a bond order of 1.5. Benzene is susceptible to attack by electrophiles (10) Carboxylic acids can be reduced to primary alcohols (via the aldehyde). Ketones can be reduced to secondary alcohols. Typical reducing agents are lithium aluminium hydride (used to reduce carboxylic acids) and sodium borohydride
(1) Explanation of why hydroxide is a better nucleophile than water (2) Deduction of the mechanism of the nucleophilic substitution reactions of halogenoalkanes with aqueous sodium hydroxide in terms of SN1 and SN2 mechanisms. Explanation of how the rate depends on the identity of the halogen (ie the leaving group), whether the halogenoalkane is primary, secondary or tertiary and the choice of solvent (3) Outline of the difference between protic and aprotic solvents (4) Deduction of the mechanism of the electrophilic addition reactions of alkenes with halogens/interhalogens and hydrogen halides (5) Deduction of the mechanism of the nitration (electrophilic substitution) reaction of benzene (using a mixture of concentrated nitric acid and sulfuric acid) (6) Writing reduction reactions of carbonyl containing compounds: aldehydes and ketones to primary and secondary alcohols and carboxylic acids to aldehydes, using suitable reducing agents (7) Conversion of nitrobenzene to phenylamine via a two-stage reaction

20.2: Synthetic routes (Higher Level)

(1) The synthesis of an organic compound stems from a readily available starting material via a series of discrete steps. Functional group interconversions are the basis of such synthetic routes (2) Retro-synthesis of organic compounds
(1) Deduction of multi-step synthetic routes given starting reagents and the product(s)

20.3: Stereoisomerism (Higher Level)

(1) Stereoisomers are subdivided into two classes—conformational isomers, which interconvert by rotation about a σ bond and configurational isomers that interconvert only by breaking and reforming a bond

(2) Configurational isomers are further subdivided into cis-trans and E/Z isomers and optical isomers

(3) Cis-trans isomers can occur in alkenes or cycloalkanes (or heteroanalogues) and differ in the positions of atoms (or groups) relative to a reference plane

(4) A chiral carbon is a carbon joined to four different atoms or groups

(5) An optically active compound can rotate the plane of polarized light as it passes through a solution of the compound. Optical isomers are enantiomers. Enantiomers are non- superimposable mirror images of each other. Diastereomers are not mirror images of each other

(6) A racemic mixture (or racemate) is a mixture of two enantiomers in equal amounts and is optically inactive

(1) Construction of 3-D models (real or virtual) of a wide range of stereoisomers (2) Explanation of stereoisomerism in non- cyclic alkenes and C3 and C4 cycloalkanes (3) Comparison between the physical and chemical properties of enantiomers (4) Description and explanation of optical isomers in simple organic molecules (5) Distinction between optical isomers using a polarimeter

Topic 11 & 21: Measurement & Data Processing

This section of the IB Chemistry syllabus focuses on the experimental aspects of science. It explores errors, measurements and techniques necessary for the IA coursework, a part of the IB Chemistry syllabus.

Understanding

Application

11.1: Uncertainties and errors in measurements and results

(1) Qualitative data includes all non- numerical information obtained from observations not from measurement (2) Quantitative data are obtained from measurements, and are always associated with random errors/uncertainties, determined by the apparatus, and by human limitations such as reaction times (3) Propagation of random errors in data processing shows the impact of the uncertainties on the final result (4) Experimental design and procedure usually lead to systematic errors in measurement, which cause a deviation in a particular direction (5) Repeat trials and measurements will reduce random errors but not systematic errors
(1) Distinction between random errors and systematic errors (2) Record uncertainties in all measurements as a range (+) to an appropriate precision (3) Discussion of ways to reduce uncertainties in an experiment (4) Propagation of uncertainties in processed data, including the use of percentage uncertainties (5) Discussion of systematic errors in all experimental work, their impact on the results and how they can be reduced (6) Estimation of whether a particular source of error is likely to have a major or minor effect on the final result (7) Calculation of percentage error when the experimental result can be compared with a theoretical or accepted result (8) Distinction between accuracy and precision in evaluating results

11.2: Graphical techniques

(1) Graphical techniques are an effective means of communicating the effect of an independent variable on a dependent variable and can lead to determination of physical quantities

(2) Sketched graphs have labelled but unscaled axes, and are used to show qualitative trends, such as variables that are proportional or inversely proportional

(3) Drawn graphs have labelled and scaled axes, and are used in quantitative measurements

(1) Drawing graphs of experimental results including the correct choice of axes and scale (2) Interpretation of graphs in terms of the relationships of dependent and independent variables (3) Production and interpretation of best-fit lines or curves through data points, including an assessment of when it can and cannot be considered as a linear function (4) Calculation of quantities from graphs by measuring slope (gradient) and intercept, including appropriate units

11.3: Spectroscopic identification of organic compounds

(1) The degree of unsaturation or index of hydrogen deficiency (IHD) can be used to determine from a molecular formula the number of rings or multiple bonds in a molecule (2) Mass spectrometry (MS), proton nuclear magnetic resonance spectroscopy (1H NMR) and infrared spectroscopy (IR) are techniques that can be used to help identify compounds and to determine their structure
(1) Determination of the IHD from a molecular formula (2) Deduction of information about the structural features of a compound from percentage composition data, MS, 1H NMR or IR

21.1: Further Spectroscopic identification (Higher Level)

(1) Structural identification of compounds involves several different analytical techniques including IR, 1H NMR and MS (2) In a high resolution 1H NMR spectrum, single peaks present in low resolution can split into further clusters of peaks (3) The structural technique of single crystal X-ray crystallography can be used to identify the bond lengths and bond angles of crystalline compounds
(1) Explanation of the use of tetramethylsilane (TMS) as the reference standard (2) Deduction of the structure of a compound given information from a range of analytical characterization techniques (X- ray crystallography, IR, 1H NMR and MS)

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