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definitions

IB Chemistry S3.2 Definitions

This page contains our IB Chemistry definitions for S3.2. By learning each one of these definitions, you will fully cover the content for IB Chemistry 'Further functional groups'.

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chiral carbon

A carbon bonded to four different groups

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cis-isomerism

Attached groups are the same on the same side of the bond plane

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cis-trans isomerism

Isomerism that only occurs with bond rotation restriction and communicates symmetry around the bond plane based on group identity

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configurational isomers

Molecules with different arrangements that require bond breaking and reforming to align

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conformational isomers

Molecules with different spatial arrangements that can be aligned by bond rotation

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diastereomer

Optical isomers that are not mirror images of each other

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E-isomerism

The groups with the highest atomic numbers are on opposite sides of the bond plane

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E/Z isomerism

Isomerism that only occurs with bond rotation restriction and communicates symmetry around the bond plane based on atomic number

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enantiomers

Optical isomers that are mirror images of each other

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fingerprint region

A unique pattern of absorption in the wavenumber region of 1400-400 cm-1

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H NMR

A method that provides information about the environment of hydrogen atoms

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hydrogen environment

The atom that the hydrogen is attached to and atoms bonded to that atom

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index of hydrogen deficiency (IHD)

A measure of saturation of an organic molecule

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infrared spectroscopy

A method that shines infrared light on molecules and measure absorption

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mass spectrometry

A method that vaporizes and ionizes a sample molecule, and then deflects its into different fragments with magnetic field

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optical isomerism

Isomerism where two molecules have the same molecular and structural formuals but are not super-imposable

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polarimeter

A device that detects the optical activity of enantiomers

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racemic mixture

A mixture with equal amounts of enantiomers, which is optically inactive

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Spin-spin coupling

Produces the splitting pattern on H-NMR due to the influence of Hydrogen nuclei on other neighbouring Hydrogen nuclei

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stereoisomers

Molecules with the same structural formula but different spatial arrangements

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trans-isomerism

Attached groups are the same on opposite sides of the bond plane

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X-ray crystallography

A method that shines X-rays on bonds and uses a sensor to detect the diffraction of the X-rays to measure bond length

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Z-isomerism

The groups with the highest atomic numbers are on the same side of the bond plane